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『壹』 鍕囧＋鐨勪俊浠板彿婧愭嫵甯堬紝緇濅笘鐑琛+10涓濂楋紝閭綆[email protected] 鏈濂芥湁鏃惰咃紝娌℃嫵甯堬紝鍓戜篃琛

瀛╁瓙銆傜粰鎴戞渶浣沖惂銆傜劧鍚庡埆姊﹀夠浜嗭紝鐜板湪姝ｅ紡鍛婅瘔浣狅紝鏈夋椂瑁呭拰緲呰唨鐨勫彿婧愭槸涓嶈兘浣跨敤鐨勩備慨鏀逛笂鍘誨悗灝辨槸甯愬彿寮傚父銆備笉鑳界櫥褰曢偅涓瀛樻。銆傝繖鏄鐪熺殑錛屾垜鑷宸辨妸鏈夌繀鑶鐨勫彿鐨勫彿婧愶紝鏀懼嚭鏉ワ紝鐢ㄥ埌鍙﹀栦竴涓鍙風粨鏋滃氨鏄鐧婚檰寮傚父銆傘傘傘傘傚叾瀹炴垜涔熸兂瑕佸搰錛岀湅鎴戞墦榪欎箞澶氬瓧錛岀粰鎴戞渶浣沖惂!鍙傝冭祫鏂欙細鏈浜鴻瘯榪囷紝綰鍘熷壋

『貳』 鐓や腑寰閲忓厓緔犲拰鐭跨墿瀵岄泦鐨勫悓娌夌Н鐏灞辯伆涓庢搗搴曞柗嫻佸嶅悎鎴愬洜

鎽 瑕 鐓や腑甯擱噺銆佸井閲忓厓緔犲拰鐭跨墿鐨勫瘜闆嗗線寰鏄澶氱嶅湴璐ㄥ洜緔犲叡鍚屼綔鐢ㄧ殑緇撴灉銆傝繍鐢ㄤ綆娓╃伆鍖栥乆灝勭嚎琛嶅皠鍒嗘瀽銆佸甫鑳借氨浠鐨勬壂鎻忕數瀛愭樉寰闀溿侀愮駭鍖栧︽彁鍙栥佺數紱昏﹀悎絳夌誨瓙浣撹川璋辯瓑鏂規硶瀵逛簯鍗楃牃灞辨櫄浜屽彔涓栫叅鐨勭熆鐗╁﹀拰鍦扮悆鍖栧︾壒寰佽繘琛屼簡鐮旂┒錛屾彁鍑轟簡鐓や腑寰閲忓厓緔犲拰鐭跨墿瀵岄泦鐨勫悓娌夌Н鐏灞辯伆涓庢搗搴曞柗嫻佸嶅悎妯″紡(鎴栨垚鍥犵被鍨)銆傜爺絀跺彂鐜幫紝鐮氬北鐭垮尯M9鐓ゅ眰紜鍒嗗惈閲忓緢楂(S_t錛宒=10.65%)錛屽睘浜庤秴楂樻湁鏈虹～鐓(S_o錛宒=9.51%)銆傜熆鐗╃粍鎴愪富瑕佹湁尾-鐭寵嫳鍓鍍忋侀忛暱鐭熾侀挔闀跨煶銆佺櫧浜戞瘝銆佷紛鍒╃煶銆侀粍閾佺熆浠ュ強灝戦噺鐨勯珮宀鐭熾佹枩闀跨煶銆侀挋闀侀粍闀跨煶銆侀噾綰㈢煶鍜岀墖閽犻摑鐭熾傜叅涓楂樺害瀵岄泦鐨勫井閲忓厓緔燜(841渭g/g)錛孷(567渭g/g)錛孋r(329渭g/g)錛孨i(74渭g/g)錛孧o(204渭g/g)鍜孶(153渭g/g)銆傝ョ叅涓鐨勭熆鐗╄川涓昏佹湁3涓鏉ユ簮:鈶犻珮娓╃煶鑻便侀忛暱鐭熾佺櫧浜戞瘝鍜屼紛鍒╃煶絳夋槸娉ョ偔鑱氱Н鏈熼棿閰告х伀灞辯伆闄嶈惤鍒版償鐐娌兼辰鍚庣殑浜х墿;鈶￠挔闀跨煶鍜岀墖閽犻摑鐭充互鍙婁互涓婅秴甯稿瘜闆嗙殑寰閲忓厓緔犳槸鍦ㄦ償鐐鑱氱Н鏈熼棿錛屽熀鎬-瓚呭熀鎬ф搗搴曞柗嫻佷鏡鍏ュ埌闂濉炵己姘х殑娉ョ偔娌兼辰涓鎵鑷;鈶㈢█鍦熷厓緔狅紝Nb錛孻錛孼r鍜孴iO₂絳変翰鐭沖厓緔犳潵婧愪簬鐩嗗湴鍗楅儴鐨勮秺鍖楀彜闄嗐傞櫎浜嗙墿婧愪緵緇欎互澶栵紝鐮氬北鐭垮尯鐓ょ殑鐭跨墿瀛﹀拰鍦扮悆鍖栧﹀紓甯告槸鍚屾矇縐閰告х伀灞辯伆鍜屽熀鎬-瓚呭熀鎬ф搗搴曞柗嫻佸叡鍚屼綔鐢ㄧ殑緇撴灉銆

浠誨痙璐葷叅宀╁﹀拰鐓ゅ湴鐞冨寲瀛﹁烘枃閫夎緫

鐓や腑甯擱噺鍜屽井閲忓厓緔犱互鍙婄熆鐗╂槸鐓ゅ艦鎴愬拰婕斿寲鍦拌川鍘嗗彶榪囩▼鐨勪駭鐗╋紝Ren絳変漢^錛1錛鍜屼換寰瘋椿絳変漢^錛2錛鎬葷粨浜嗙叅涓寰閲忓厓緔犲瘜闆嗙殑鎴愬洜鏈虹悊錛屽苟鎻愬嚭浜5縐嶅瘜闆嗘ā寮忥紝鍗抽檰婧愬瘜闆嗗瀷銆佹矇縐鐨勭敓鐗╀綔鐢ㄥ瘜闆嗗瀷銆佸博嫻嗙儹娑蹭綔鐢ㄥ瘜闆嗗瀷銆佹繁澶ф柇瑁-鐑娑蹭綔鐢ㄥ瘜闆嗗瀷鍜屽湴涓嬫按浣滅敤瀵岄泦鍨嬨傚惈鐓ゅ湴灞備腑鐨勭伀灞辯伆鋩鍙橀粡鍦熷博澶圭煾(Tonstein)瀵圭爺絀跺尯鍩熷湴璐ㄥ巻鍙叉紨鍖栧拰鐓ゅ眰瀵規瘮絳夋柟闈㈠叿鏈夐噸瑕佷綔鐢^錛3錛4錛銆傚逛腑鍥借タ鍗楀湴鍖烘櫄浜屽彔涓栫叅涓鍙戣偛鐨凾onstein鐨勭爺絀惰〃鏄^錛4鍀6錛錛屾櫄浜屽彔涓栨棭鏈熺殑鐏灞卞柗鍙戜互紕辨х伀灞辯伆涓轟富錛屾櫄浜屽彔涓栦腑鏅氭湡浠ラ吀鎬т負涓匯傜叅涓鐨凾onstein鍙鑳戒細瀵圭叅鐨勫湴鐞冨寲瀛︾壒寰佷駭鐢熼噸瑕佸獎鍝^錛7錛銆傚獎鍝嶈タ鍗楀湴鍖烘櫄浜屽彔涓栫叅涓寰閲忛噾灞炲厓緔犲瘜闆嗙殑鍥犵礌寰堝氾紝浣嗕綆娓╃儹娑叉槸涓繪帶鍥犵礌^錛8錛9錛銆傝祴瀛樺湪鐓や腑鐨勫悓娌夌Н鐏灞辯伆(鍒嗗竷鍦ㄧ叅涓鏈夋満璐ㄤ腑鐨勭伀灞辯伆錛屼笉鍖呮嫭Tonstein)鏈夎緝灝戞姤閬^錛7錛錛岃屾搗搴曞柗嫻佸圭叅涓鐭跨墿鍜屽厓緔犲瘜闆嗙殑褰卞搷灝氭湭瑙佽告姤閬撱傛湰鏂囧逛簯鍗楃牃灞卞矓闄愮⒊閰哥洂鍙板湴鍨嬬叅灞傜殑鐭跨墿瀛﹀拰鍦扮悆鍖栧﹁繘琛屼簡鐮旂┒錛屾彁鍑轟簡鐓や腑鐭跨墿鍜屽井閲忓厓緔犲瘜闆嗙殑鍚屾矇縐鐏灞辯伆涓庢搗搴曞柗嫻佸嶅悎妯″紡銆傝ユ枃鎻愬嚭鐨勭叅涓寰閲忓厓緔犲拰鐭跨墿鐨勫瘜闆嗘ā寮忥紝鍙浠ヤ負鏂板瀷閲戝睘鐭垮簥鐨勫繪壘鎻愪緵鍊熼壌銆

涓銆佸湴璐ㄨ儗鏅

鐮氬北鐭垮尯浣嶄簬浜戝崡鐪佷笢鍗楅儴(鍥1)錛屽叾鍚鐓ゅ湴灞備負涓婁簩鍙犵粺鍚村跺潽緇(P₂^w)鍜岄暱鍏寸粍(P₂^ch)^錛10錛錛岃ュ尯M9鐓ゅ眰鏄鍏稿瀷鐨勫矓闄愮⒊閰哥洂鍙板湴鍨嬬叅灞傘侻9鐓ゅ眰浣嶄簬涓婁簩鍙犵粺鍚村跺潽緇勭殑涓閮錛屽帤搴︿負1.91m錛屽叾欏舵澘涓哄瘜鍚鐢熺墿紕庡睉鐨勯殣鏅剁伆宀╋紝搴曟澘涓虹偔璐ㄦ償宀╂垨鍚鐐娉ョ伆宀┿傚惈鐓ゆ矇縐鐨勪富瑕佺墿婧愭潵鑷鐩嗗湴鍗楅儴鐨勮秺鍖楀彜闄(鍥1)銆

鍥1 鐮氬北鐭垮尯浣嶇疆鍥懼拰鏅氫簩鍙犱笘鍙ゅ湴鐞嗗浘

浜屻佺爺絀舵柟娉

鍏遍噰闆嗙牃灞卞共娌矼9鐓ゅ眰鍏ㄥ眰鍒繪Ы鏍峰搧3涓錛岀紪鍙峰垎鍒涓篩S-1錛孻S-2鍜孻G銆傚悓鏃訛紝鑷涓婅屼笅鍏遍噰鍒嗗眰鍒繪Ы鏍峰搧3涓錛岀紪鍙峰垎鍒鏄痀-3-1錛孻-3-2鍜孻-3-3錛岃繖3涓鍒嗗眰鐨勫帤搴﹀垎鍒涓0.70錛0.67鍜0.54m銆

榪愮敤鍏夊︽樉寰闀溿佸甫鑳借氨浠鐨勬壂鎻忕數瀛愭樉寰闀溿佷綆娓╃伆鍖栧拰X灝勭嚎琛嶅皠浠瀵圭熆鐗╃殑縐嶇被銆佸瓨鍦ㄧ姸鎬佽繘琛屼簡鐮旂┒銆傚埄鐢ㄦ樉寰闀滃厜搴﹁″圭叅涓鏄懼井緇勫垎鐨勫艦鎬佸拰闀滆川緇勫弽灝勭巼榪涜屼簡嫻嬪畾銆傝繍鐢╔灝勭嚎鑽у厜鍏夎氨浠瀵圭叅涓甯擱噺鍏冪礌鐨勫惈閲忚繘琛屼簡嫻嬪畾錛孎鍜孒g鍒嗗埆榪愮敤紱誨瓙閫夋嫨鎬х數鏋佸拰鍐峰師瀛愬惛鏀跺厜璋辨硶榪涜屼簡嫻嬪畾錛孋l閲囩敤鑹懼＋鍗℃販鍚堝墏鐔旀牱-紜姘伴吀閽炬淮瀹氭硶嫻嬪畾;B鍒╃敤鐢電昏﹀悎絳夌誨瓙浣撳師瀛愬彂灝勫厜璋辨祴瀹;鍏朵粬寰閲忓厓緔犻噰鐢ㄧ數紱昏﹀悎絳夌誨瓙浣撹川璋辮繘琛屼簡嫻嬪畾銆

涓夈佺粨鏋滀笌璁ㄨ

1.鐓ゅ寲瀛︾壒寰

浜戝崡鐮氬北鏅氫簩鍙犱笘M9鐓ゅ睘浜庝腑鐏(27.51%)銆侀珮紜(10.65%)鐨勯珮鐓ゅ寲紼嬪害鐨勭儫鐓(璐鐓)銆傜敱浜嶮9鐓ゅ眰涓鏈夋満紜鍚閲忛珮杈9.51%錛屽張縐頒箣涓鴻秴楂樻湁鏈虹～鐓(琛1)銆傝繖縐嶈秴楂樻湁鏈虹～鐓ゅ湪鑷鐒剁晫涓闈炲父緗曡併傚湪涓鍥斤紝姝ょ被鍨嬬叅浠呭湪璐靛窞璐靛畾(S_o錛宒=8.57%)鍜屽箍瑗垮悎灞(S_o錛宒=3.42%鍀6.46%)鏈夋姤閬^{錛11錛12錛}銆

琛1 浜戝崡鐮氬北鏅氫簩鍙犱笘M9鐓ょ殑宸ヤ笟鍒嗘瀽銆佸叏紜鍜屽艦鎬佺～嫻嬭瘯緇撴灉 鍗曚綅:%

娉:6涓鏍峰搧鍧囧.M鈥旀按鍒;A鈥旂伆鍒;V鈥旀尌鍙戝垎;S_t鈥斿叏紜;S_s鈥旂～閰哥洂紜;S_p鈥旂～鍖栫墿紜;S_o鈥旀湁鏈虹～;ad鈥斿垎鏋愬熀;d鈥斿共鐕ュ熀;daf鈥斿共鐕ユ棤鐏板熀銆

2.鐓や腑鐭跨墿鐨勭嶇被銆佽祴瀛樼壒寰佸拰鎴愬洜

鐓や腑甯歌佺殑鐭跨墿涓鑸鏈夐粡鍦熺熆鐗┿佺～鍖栫墿鐭跨墿銆佺煶鑻卞拰鏂硅В鐭^錛13錛銆傚埄鐢ㄤ綆娓╃伆鍖+X灝勭嚎琛嶅皠鍒嗘瀽銆佸厜瀛︽樉寰闀滃拰甯﹁兘璋變華鐨勬壂鎻忕數瀛愭樉寰闀滆傚療鍚庡彂鐜幫紝鐮氬北M9鐓ゅ眰涓鐨勭熆鐗╃粍鍚堣緝涓哄紓甯革紝涓昏佺熆鐗╂湁閫忛暱鐭熾佄-鐭寵嫳鍓鍍忋佺櫧浜戞瘝銆佷紛鍒╃煶銆侀挔闀跨煶銆侀粍閾佺熆錛岃繕鏈夊皯閲忕殑鐗囬挔閾濈煶銆佹枩闀跨煶銆侀挋闀侀粍闀跨煶銆侀攼閽涚熆鍜岄噾綰㈢煶銆

榛勯搧鐭:涓昏佸憟嫻告煋鐘舵垨鑾撶悆鐘跺垎甯冨湪鍩鴻川闀滆川浣撲腑錛屽叾綺掑緞杈冨皬錛屽ぇ閮ㄥ垎灝忎簬20渭m銆傜叅涓榛勯搧鐭跨殑璧嬪瓨褰㈡佽〃鏄庯紝瀹冨睘浜庢搗姘村獎鍝嶄笅鐨勪駭鐗┿傛償鐐鑱氱Н鏈熼棿錛屾搗姘翠腑鐨勭～閰告牴紱誨瓙琚紜閰哥洂榪樺師鑿岃繕鍘熸垚紜鍖栨阿鍚庝笌娌兼辰涓鐨凢e紱誨瓙鍙嶅簲鑰屽艦鎴^錛14錛銆

尾-鐭寵嫳鍓鍍:涓昏佸憟緇嗗皬鐨勩佹櫠鍨嬭緝濂界殑棰楃矑鍒嗗竷鍦ㄥ熀璐ㄩ暅璐ㄤ綋涓錛屽叾緇濆ぇ閮ㄥ垎棰楃矑灝忎簬10渭m錛屾í鍒囬潰榪戝叚杈瑰艦(鍥2(a))錛屾湁鐨勬湁鐔旇殌鐜拌薄銆佹熅闈涓嶅彂鑲層備粠鍏跺艦鎬佺壒寰佸彲浠ユ帹鏂灞炰簬楂樻俯鎴愬洜銆

閫忛暱鐭:綺掑緞杈冨皬錛岀粷澶ч儴鍒嗗皬浜10渭m錛屾湁鐨勬櫠褰淇濆瓨杈冨ソ(鍥2(b)錛(c))錛屾湁鐨勫彂鐢熶簡鐔旇殌錛岃鐔旇殌鐨勯忛暱鐭蟲湁鏃朵粎淇濈暀妯＄硦鐨勫栧艦錛屾湁鐨勯忛暱鐭崇啍鋩鐜拌薄杈冧負涓ラ噸錛屼粎鐣欐湁孌嬬己涓嶅叏鐨勮竟緙橈紝鍐呴儴琚閽犻暱鐭蟲墍鏇誇唬鎴栫墖閽犻摑鐭(NaAl(OH)₂CO₃)鎵鍏呭～(鍥2(c))銆

鐧戒簯姣:鍛堥暱鏉＄姸鍒嗗竷鍦ㄥ熀璐ㄩ暅璐ㄤ綋涓銆

閽犻暱鐭:鏅跺艦杈冮忛暱鐭沖畬鏁(鍥2(d))錛岀畝鍗曞弻鏅跺彂鑲詫紝閮ㄥ垎閽犻暱鐭沖彂鐢熶簡鐔旇殌鐜拌薄(鍥2(c))錛屾湁鐨勯挔闀跨煶鍏呭～鍦ㄨ鐔旇殌浜嗙殑閫忛暱鐭沖唴閮ㄣ

浼婂埄鐭:鍛堜笉瑙勫垯鍥㈠潡鐘躲侀暱鏉＄姸銆佺誕鍑濈姸(鍥2(e))鎴栨蹈鏌撶姸鍒嗗竷鍦ㄧ叅鐨勫熀璐ㄩ暅璐ㄤ綋涓銆

姝ゅ栵紝M9鐓ゅ眰涓榪樻湁灝戦噺鐨勬枩闀跨煶銆侀噾綰㈢煶銆侀挋闀侀粍闀跨煶鍜岄珮宀鐭崇瓑鐭跨墿鍒嗗竷鍦ㄥ熀璐ㄩ暅璐ㄤ綋涓銆

鉶界劧鐓ょ郴鍦板眰涓閰告х伀灞辯伆鋩鍙橀粡鍦熷博澶圭煾涓鐨勯珮娓╃煶鑻遍潪甯告櫘閬^錛3錛15錛錛屼絾鍦ㄧ叅涓鍜屾湁鏈鴻川緔у瘑鑱旂郴鐨勯珮娓╂垚鍥犵殑鐭寵嫳鍗撮矞鏈夋姤閬撱傜牃灞盡9鐓ゅ眰涓楂樻俯鎴愬洜鐨勭煶鑻卞叾澶栧艦浠嶇劧渚澪茬煶鑻辨垚鍓鍍(鍥2(a))銆偽茬煶鑻卞拰閫忛暱鐭蟲槸楂樻俯鐩哥殑浜х墿銆傝ョ叅涓楂樻俯鐭寵嫳-閫忛暱鐭-鐧戒簯姣嶇熆鐗╃粍鍚堟槸娉ョ偔鑱氱Н鏈熼棿閰告х伀灞辯伆闄嶈惤鍒版布娉戒腑鐨勪駭鐗┿傜敱浜庤繖浜涚熆鐗╃殑綺掑緞寰堝皬錛屽苟涓斿潎鍖鍦板垎甯冨湪鐓ょ殑鏈夋満璐ㄤ腑錛屾帹嫻嬪綋鏃剁殑鐏灞卞彛璺濇布娉借緝榪滐紝騫朵笖闄嶈惤鍒版布娉戒腑鐨勭伀灞辯伆鐨勬暟閲忚緝灝戱紝灝氫笉瓚充互褰㈡垚鎵璋撶殑鐏灞辯伆鋩鍙橀粡鍦熷博澶圭煾(Tonstein)銆傚湪M9鐓ゅ眰涓灝氭湭鍙戠幇Tonstein灞傦紝鐮氬北鐭垮尯浣嶄簬涓嶼hou絳変漢^錛4錛鎵鍦堝畾鐨勮タ鍗楀湴鍖篢onstein鐨勫垎甯冭寖鍥翠箣澶栵紝鑰屽湪姝よ寖鍥村唴錛屾櫄浜屽彔涓栫伀灞辨椿鍔ㄨ緝涓哄己鐑堬紝鍦ㄧ叅灞備腑褰㈡垚澶氬眰鐨凾onstein銆

鍥2 M9鐓や腑鐨勭熆鐗╄祴瀛樼壒寰

闄嗘簮紕庡睉渚涚粰鍜屽悗鐢熶綔鐢ㄧ瓑鍧囧彲鍦ㄧ叅涓褰㈡垚浼婂埄鐭^錛13錛銆備絾M9鐓ゅ眰涓鐨勪紛鍒╃煶騫墮潪闄嗘簮紕庡睉鎴愬洜錛屼篃涓嶆槸鍚庢湡鐑娑蹭綔鐢ㄧ殑浜х墿銆傞檷钀藉埌M9鐓ゅ眰鐨勬布娉戒腑鐨勯吀鎬х伀灞辯伆鐜葷拑璐ㄥ湪娉ョ偔鑱氱Н鏈熼棿鍜屾垚宀╀綔鐢ㄦ棭鏈熻殌鍙樺艦鎴愰珮宀鐭籌紝闅忕潃鎴愬博浣滅敤鐨勫炲己鍜屽湪鍋忕⒈鎬х殑浠嬭川鐜澧冩潯浠朵笅錛屽ぇ閮ㄥ垎楂樺箔鐭寵漿鍙樹負浼婂埄鐭籌紝鏈変簺浼婂埄鐭寵繕淇濈暀鐫鐏灞辯伆緄鍑濈姸鐨勭粨鏋勭壒寰(鍥2(e))銆侭urger絳変漢^錛5錛銆佸懆涔夊鉤鍜屼換鍙嬭皡^錛6錛鐨勭爺絀惰〃鏄庯紝鍦ㄤ簯鍗椾笢閮ㄥ拰璐靛窞瑗塊儴涓婁簩鍙犵粺鐓ょ郴鍦板眰鐨凾onstein涓榛忓湡鐭跨墿(楂樺箔鐭-浼婂埄鐭)鐨勭粍鎴愭瘮渚嬩笌鐓ょ殑鍙樿川紼嬪害瀵嗗垏鐩稿叧錛屽湪鐑熺叅闃舵碉紝楂樺箔鐭沖崰浼樺娍錛屽埌鏃犵儫鐓ら樁孌碉紝緇濆ぇ閮ㄥ垎楂樺箔鐭寵殌鍙樹負浼婂埄鐭熾傜牃灞盡9鐓や腑鐏灞辯伆鎬ц川鍜岃タ鍗楀湴鍖虹殑鐏灞卞柗鍙戠墿鐨勭壒寰佺浉鍚誨悎錛屽嵆鍦ㄦ櫄浜屽彔涓栦腑鏅氭湡浠ラ吀鎬т負涓匯

鐓や腑鐨勯暱鐭沖拰鐧戒簯姣嶄竴鑸琚璁や負鏄闄嗘簮紕庡睉鎴愬洜鐨勭熆鐗^{錛13錛16錛}銆備絾鐮氬北M9鐓ゅ眰涓鐨勯暱鐭沖苟闈為檰婧愮庡睉鎴愬洜銆侻9鐓や腑鐨勯挔闀跨煶涓庣伀灞辨垚鍥犵殑閫忛暱鐭熾侀珮娓╃煶鑻變害涓嶆槸鍚屾湡鎴愬洜鐨勪駭鐗┿傞挔闀跨煶鏈夋椂鍏呭～鍦ㄨ鐔旇殌鐨勯忛暱鐭沖唴閮錛屾槸鍦ㄩ忛暱鐭沖彂鐢熸憾鋩鍚庡艦鎴愮殑錛屽叾褰㈡垚鏃墮棿鏅氫簬閫忛暱鐭籌紝琛ㄦ槑閽犻暱鐭蟲槸浠庣儹娑蹭腑鑷鐢熺殑銆傚洜姝わ紝鍙浠ユ帹鏂鍦ㄦ償鐐鑱氱Н鏈熼棿錛岀伀灞辯伆闄嶈惤鍒版償鐐娌兼辰騫朵笖緇忚繃浜嗕竴瀹氱殑鋩鍙樹綔鐢ㄥ悗錛屽張鏈夊熀鎬-瓚呭熀鎬х殑嫻峰簳鍠鋒祦褰㈡垚鐨勭儹娑茶繘鍏ュ埌娉ョ偔娌兼辰涓錛屽艦鎴愪簡閽犻暱鐭沖拰灝戦噺鐨勭墖閽犻摑鐭沖拰鏂滈暱鐭崇瓑鐭跨墿銆傜墖閽犻摑鐭沖湪鐓や腑灝氭湭瑙佽告姤閬^{錛13錛17錛18錛}錛屾槸涓縐嶆按鐑鎴愬洜鐨勭熆鐗^{錛19鍀21錛}銆傜墖閽犻摑鐭寵板綍浜嗘繁閮ㄥ箶婧-嫻呴儴澹蟲簮涔嬮棿鐨勭墿璐ㄨ漿縐伙紝鏄嫻佷綋榪愮Щ鍚庣暀涓嬬殑浜х墿錛屽苟涓斿艦鎴愪簬瀵岄挔紱誨瓙鐨勭⒈鎬ф祦浣撲粙璐ㄦ潯浠^{錛21錛22錛}錛岃ョ熆鐗╃殑瀛樺湪榪涗竴姝ヨ瘉鏄庝簡嫻峰簳鍠鋒祦渚靛叆鍒頒簡娉ョ偔娌兼辰銆

鐗囬挔閾濈煶鍜岄挔闀跨煶鐨勮祴瀛樼姸鎬佹帓闄や簡榪欎袱縐嶇熆鐗╁睘浜庡悗鐢熺儹娑茬殑鍙鑳芥:鈶燤9鐓や腑鐨勫悗鐢熻傞殭鏋佷笉鍙戣偛錛屽皻鏈鍙戠幇鍏呭～浜庡悗鐢熻傞殭鐨勯暱鐭沖拰鐗囬挔閾濈煶;鈶￠挔闀跨煶鍦ㄧ叅灞備腑欏哄眰鐞嗗垎甯(鍥2(f))錛屾樉紺哄嚭鍚屾矇縐鐨勭壒寰侊紝鑰岄潪鍚庣敓鐑娑叉垚鍥;鈶㈣ョ叅涓鐨勭熆鐗╃粍鎴愮殑騫抽潰鍒嗗竷鐨勫樊寮傛ф瀬涓嶆槑鏄撅紝閽犻暱鐭沖湪璇ョ叅灞備腑鏅閬嶅瓨鍦錛屽湪鐮旂┒鑰1988騫撮噰闆嗙殑鏍峰搧鍜2006騫撮噰闆嗙殑鏍峰搧涓鍧囧瘜闆嗛挔闀跨煶絳夌熆鐗(鏍峰搧閲囬泦闂撮殧18a);鑰屽悗鐢熺儹娑叉垚鍥犵殑鐭跨墿寰寰鍦ㄧ叅灞備腑鍏鋒湁灞閮ㄥ瘜闆嗙殑鐗瑰緛錛屽惈閲忓垎寮傛槑鏄俱

3.鐓や腑甯擱噺鍜屽井閲忓厓緔犵殑涓板害銆佽祴瀛樼姸鎬佸拰鎴愬洜

琛2鍒楀嚭浜嗙牃灞盡9鐓や腑甯擱噺鍏冪礌鍜屽井閲忓厓緔犵殑鍚閲忓強鍏朵笌涓鍥藉ぇ閮ㄥ垎鐓ゃ佷笘鐣屽ぇ閮ㄥ垎鐓ょ殑瀵規瘮銆備粠涓鍙浠ョ湅鍑猴紝鐮氬北騫叉渤M9鐓や腑鐨勫厓緔犳湁濡備笅鐗瑰緛:涓庝腑鍥藉ぇ閮ㄥ垎鐓ゅ拰涓栫晫澶ч儴鍒嗙叅涓寰閲忓厓緔犵殑鍧囧肩浉姣旓紝鐮氬北鐓や腑F(841渭g/g)錛孷(567渭g/g)錛孋r(329渭g/g)錛孨i(74渭g/g)錛孧o(204渭g/g)鍜孶(153渭g/g)絳夊井閲忓厓緔犵殑鍚閲忚秴甯稿瘜闆(琛2)銆傝ョ叅涓璙錛孋r錛孧o鍜孶鐨勫潎鍊煎垎鍒鏄涓鍥藉父瑙佺叅鐨16.2鍊嶃21.4鍊嶃63.9鍊嶅拰63.5鍊嶃

鉶界劧闄嗘簮紕庡睉渚涚粰閫氬父鏄鐓や腑寰閲忓厓緔犵殑涓涓閲嶈佹潵婧愶紝鐮氬北M9鐓や腑鐨勭█鍦熷厓緔狅紝Nb錛孻錛孼r鍜孴iO₂絳変翰鐭沖厓緔犲弽鏄犱簡瓚婂寳鍙ら檰鐗╂簮鐗╄川緇勬垚鐗瑰緛銆傝秺鍖楀彜闄嗘槸鍔犻噷涓滆ざ鐨卞甫娉告睙甯︼紝浠ラ吀鎬у博浣撲負涓^{錛25錛26錛}銆備絾鐮氬北鐓や腑楂樺惈閲忕殑V錛孨i錛孋r錛孧o鍜孶鏄涓嶈兘鐢ㄩ檰婧愪緵緇欐墍鑳借В閲婄殑銆備笌瓚呭熀鎬у拰鍩烘у博鐩告瘮錛岄吀鎬у博涓鐨刅錛孨i錛孧o錛孋r絳夊厓緔犲潎杈冧綆錛孶鐨勫惈閲忚櫧鐒惰緝楂橈紝浣嗗叾鍚閲忎篃浠呬負3.5渭g/g^錛27錛錛屼笉瓚充互鎻愪緵鐓や腑濡傛ら珮鍚閲忕殑U銆

榪欎簺楂樺惈閲忕殑鍏冪礌涔熶笉鏄涓婇潰鎵鍙欒堪鐨勯吀鎬х伀灞辯伆闄嶈惤鍒版償鐐娌兼辰褰㈡垚鐨勶紝閰告х伀灞辯伆騫朵笉瀵岄泦榪欎簺鍏冪礌錛屼綍鍐甸檷钀藉埌娉ョ偔娌兼辰涓鐨勯吀鎬х伀灞辯伆鐨勯噺姣旇緝灝戙

灝氭棤璇佹嵁琛ㄦ槑榪欎簺鍏冪礌鏄鍦板栨潵婧愩傝繖浜涘厓緔(鍖呮嫭S鍦ㄥ唴)涔熶笉鏄姝ｅ父嫻鋒按鑳藉熸彁渚涚殑錛屾搗姘翠腑鐨勭～閰哥洂嫻撳害鏄涓瀹氱殑錛屽苟涓旀償鐐鑱氱Н鏄鍦ㄤ竴縐嶆粸鐣欑殑銆佸彈闄愮殑灞闄愮⒊閰哥洂鍙板湴錛屽獎鍝嶆償鐐娌兼辰鐨勬柊椴滄搗姘村苟涓嶈兘寰楀埌鍙婃椂鐨勮ˉ鍏呫

琛2 鐮氬北M9鐓ゅ眰鍏冪礌鐨勫惈閲忓強鍏朵笌涓鍥藉ぇ閮ㄥ垎鐓ゃ佷笘鐣屽ぇ閮ㄥ垎鐓ょ殑瀵規瘮

鐮氬北M9鐓ゅ眰涓瀵岄泦鐨勫厓緔犲強鍏跺厓緔犵殑緇勫悎鐗瑰緛綾諱技浜庝腑鍥藉崡鏂規棭瀵掓︾邯鐨勯粦鑹查〉宀(鍖呮嫭鐭崇叅)錛岀劧鑰岀牃灞辯叅涓鍏冪礌姣旈粦鑹查〉宀╀腑鐨勮祴瀛樺艦寮忓拰鏉ユ簮澶嶆潅寰楀氾紝鏃㈡湁鐏灞辯殑銆侀檰婧愮庡睉鐨勩佺敓鐗╃殑銆佹搗姘寸殑錛岃繕鏈夋搗搴曞柗嫻佺殑銆傜牃灞辯叅鐨勫湴鐞冨寲瀛﹀紓甯稿彲鑳芥槸鍦ㄦ償鐐鑱氱Н鏈熼棿錛屾搗搴曞柗嫻佹惡甯︾殑閲戝睘鍏冪礌V錛孨i錛孧o錛孶錛孋r浠ュ強S鍜孎絳夋部娣卞ぇ鏂瑁傛惉榪愭矇縐鑷蟲償鐐娌兼辰鐨勭粨鏋溿傛搗搴曞柗嫻佷粠闀侀搧璐-瓚呴晛閾佽川宀╀腑娣鍙栦簡V錛孨i錛孋u鍜孧o錛屽苟鍙鑳戒笌涓嬩紡鐨勫瘜U鐨勫博嫻嗗眰鎻愪緵鐨勭墿璐ㄦ販鍚堝湪涓璧鳳紝鎼榪愭矇縐鍒板矓闄愮⒊閰哥洂鍙板湴鐨勬償鐐娌兼辰涓錛岀己姘х殑鐜澧冨拰娌兼辰涓涓板瘜鐨勬湁鏈鴻川(楂樼瓑妞嶇墿鍜屼綆絳夌敓鐗╄弻鈃葷被)涓哄厓緔犵殑闀挎椂闂存椿鍖栧拰瀵岄泦鎻愪緵浜嗘潯浠躲傞矋瀛︽槶絳変漢^錛28錛鐮旂┒琛ㄦ槑錛屾搗搴曞柗嫻佷綔鐢ㄥ彲甯︽潵澶ч噺鐨刄鍏冪礌銆

鉶界劧浣庣瓑鐢熺墿瀵規湁鏈虹～鍜屼竴浜涢噾灞炲厓緔犲瘜闆嗘湁璐＄尞錛屼絾M9鐓や腑濡傛ら珮鍚閲忕殑紜鍜岄噾灞炲厓緔犱篃涓嶆槸紜緇嗚弻鎵鑳藉熸彁渚涚殑銆傝ョ叅灞傜殑騫查叒鏍刮¹³C鈥(PDB)鍊間負錛22.8鈥幫綖錛23.7鈥幫紝N鐨勫惈閲忓苟涓嶉珮(0.67%鍀0.69%)錛屽叿鏈夎厫孌栫叅鐨勭壒寰侊紝鍥犳ゆ垚鐓ゆ嶇墿鐨勪富浣撹繕鏄楂樼瓑妞嶇墿銆備絾鏄錛岃弻鈃葷被鍦ㄥ叾鐢熼暱鍜屾諱骸鍚庨檷瑙ｈ繃紼嬩腑錛屽彲鍦ㄥ厓緔犲瘜闆嗐佹敼鍙樼幆澧僷H鍜孍h鍊箋佹敼鍙樻按浣撲腑鍏冪礌騫寵緋葷粺鍜屽厓緔犳矇娣絳夋柟闈㈠圭叅涓鏈夋満紜鍜岄噾灞炲厓緔犵殑瀵岄泦鍙戞尌閲嶈佷綔鐢ㄣ

鍦ㄥ井閲忓厓緔犵殑緇勫悎鏂歸潰錛屼互鏈夋満鎬佺粨鍚堢殑V/(V+Ni)=0.88錛岀己姘х幆澧冧腑鏈夋満璐ㄧ殑V/(V+Ni)>0.5錛岃屾哀鍖栨潯浠朵笅<0.4^錛29錛銆備粠鐮氬北M9鐓ょ殑U/Th鍏崇郴(鍥3)涓鍙浠ョ湅鍑猴紝鎶曠偣鍧囪惤鍏U/Th=1鍀100鍖哄煙錛屽彟澶栵紝U/Th姣斿煎緢楂(8.9鍀35.2)錛岃存槑娉ョ偔鑱氱Н鏃跺彈鍒扮儹娑插獎鍝嶈緝涓哄己鐑^{錛30錛31錛}銆傜敤Th-U鐨勫叧緋誨紡U_a=U_Total鈥揟h/3(鍏朵腑U_a涓鴻嚜鐢烾)鍙浠ヨ存槑緙烘哀鏉′歡^錛32錛錛孧9鐓ょ殑U_a涓107鍀176渭g/g錛岃孧7鐓ょ殑U_a浠呬負17渭g/g錛岃〃鏄嶮9鐓ょ殑娉ョ偔鑱氱Н鏃舵樉钁楃己姘с

灝嗙牃灞盡9鐓ゅ眰涓鐨刏n錛孨i鍜孋o鍏冪礌鍚閲忔姇鍏Cronan鐨刏n-Ni-Co涓夊厓鍥句腑(鍥4)錛岃繖浜涚偣鍧囪惤鍏ョ儹姘存矇縐鍖猴紝鏄劇ず浜嗙儹姘存矇縐鐨勭壒寰^錛33錛銆

鍥3 鐮氬北M9鐓ゅ眰鐨刄/Th鍏崇郴鍥

鍥4 鐮氬北M9鐓ゅ眰鐨刏n-Ni-Co鍥捐В

鍏充簬紜鐨勬潵婧愬拰璧嬪瓨鐘舵侊紝鐢變簬鐜拌岀殑鏈夋満紜鍚閲忕殑紜瀹氭柟娉(GB/T214錛1996錛孏B/T215錛2003鍜孉STMD3177/4239鍜孌2492錛2)鏄鐢ㄥ叏紜鍑忕～鍖栫墿紜鍜岀～閰哥洂紜鎵鑾峰緱鐨勶紝榪欎簺鏂規硶灝氫笉鑳借瘉鏄庤繖浜涚～灝辨槸鏈夋満鐨勩傜牃灞盡9鐓や腑鐨勮祴瀛樼姸鎬佸煎緱娣卞叆鐮旂┒銆傝繖浜涢珮鍚閲忕殑紜鍙鑳芥槸嫻峰簳鐑娉夊甫鍏ュ埌灝侀棴鐨勬布娉戒腑錛屽苟涓斿潎鍖鍦板垎甯冨湪鐓ょ殑鏈夋満璐ㄤ腑錛岃岃璁や負鏄鎵璋撶殑鈥滄湁鏈虹～鈥濄

緇間笂鎵榪幫紝浜戝崡鐮氬北M9鐓ゅ眰鐨勭熆鐗╃粍鎴愬拰涓浜涘厓緔犵殑瓚呭父瀵岄泦鏄鍚屾矇縐鐏灞辯伆涓庢搗搴曞柗嫻佸叡鍚屼綔鐢ㄧ殑緇撴灉錛岃ョ叅灞傜熆鐗╄川鐨勫瘜闆嗘垚鍥犳槸涓縐嶆柊鐨勫嶅悎瀵岄泦妯″紡銆傝嚦浜庤吹宸炶吹瀹氬拰騫胯タ鍚堝北鏅氫簩鍙犱笘鐓ゆ槸鍚﹀彈鍒板悓娌夌Н閰告х伀灞辯伆鐨勫獎鍝嶈繕闇榪涗竴姝ョ爺絀躲

鍦ㄧ叅涓寰閲忓厓緔犵殑鍒╃敤鏂歸潰錛岀敱浜庤ョ叅涓鐨刅錛孋r鍜孶鍚閲忓緢楂橈紝瀹冧滑鍦ㄧ叅鐨勭噧鐑т駭鐗(濡傞炵伆)涓鍙鑳借繘涓姝ュ瘜闆嗭紝濡傛灉鑳藉硅繖浜涘厓緔犺繘琛屾彁鍙栵紝鍙浠ュ疄鐜扮叅鐐緇忔祹鐨勮壇鎬у驚鐜鍙戝睍錛屼篃涓烘柊綾誨瀷鐨勯噾灞炵熆搴婄爺鍙戞彁渚涘熼壌銆

鍥涖佺粨璁

浜戝崡鐮氬北M9鐓ゆ槸灞闄愮⒊閰哥洂鍙板湴鍩虹涓婂艦鎴愮殑鐓ゅ眰錛屽睘浜庤秴楂樷滄湁鏈虹～鈥濈叅銆傝ョ叅涓鐭跨墿鐨勭嶇被鍜岀粍鍚堢壒寰(尾-鐭寵嫳鍓鍍忋侀忛暱鐭熾侀挔闀跨煶銆佺櫧浜戞瘝銆佷紛鍒╃煶銆佹枩闀跨煶銆侀挋闀侀粍闀跨煶銆佺墖閽犻摑鐭)鍜岃秴甯稿瘜闆嗗井閲忓厓緔(F錛孷錛孋r錛孨i錛孧o鍜孶)鏄鍚屾矇縐閰告х伀灞辯伆鍜屾搗搴曞柗嫻佸叡鍚屼綔鐢ㄧ殑緇撴灉銆傝ョ叅灞備腑鐨勫井閲忓厓緔犲拰鐭跨墿鐨勫瘜闆嗘垚鍥犳満鍒舵槸涓縐嶆柊鐨勫瘜闆嗘ā寮(鎴栨垚鍥犵被鍨)銆

鍙 鑰 鏂 鐚

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( 鏈鏂囩敱浠ｄ笘宄般佷換寰瘋椿銆佸懆涔夊鉤銆丆hen-Lin Chou銆佺帇瑗垮媰銆佽檔鈒俱佹湵鍏翠紵鍚堣憲錛屽師杞姐婄戝﹂氭姤銆嬶紝2008 騫寸 53 鍗風 24 鏈)