『壹』 鍕囧＋鐨勪俊浠板彿婧愭嫵甯堬紝缁濅笘鐑琛+10涓濂楋紝閭绠[email protected] 鏈濂芥湁鏃惰咃紝娌℃嫵甯堬紝鍓戜篃琛
瀛╁瓙銆傜粰鎴戞渶浣冲惂銆傜劧鍚庡埆姊﹀够浜嗭紝鐜板湪姝ｅ紡鍛婅瘔浣狅紝鏈夋椂瑁呭拰缈呰唨鐨勫彿婧愭槸涓嶈兘浣跨敤鐨勩備慨鏀逛笂鍘诲悗灏辨槸甯愬彿寮傚父銆備笉鑳界櫥褰曢偅涓瀛樻。銆傝繖鏄鐪熺殑锛屾垜鑷宸辨妸鏈夌繀鑶鐨勫彿鐨勫彿婧愶紝鏀惧嚭鏉ワ紝鐢ㄥ埌鍙﹀栦竴涓鍙风粨鏋滃氨鏄鐧婚檰寮傚父銆傘傘傘傘傚叾瀹炴垜涔熸兂瑕佸搰锛岀湅鎴戞墦杩欎箞澶氬瓧锛岀粰鎴戞渶浣冲惂!鍙傝冭祫鏂欙細鏈浜鸿瘯杩囷紝绾鍘熷垱
『贰』 鐓や腑寰閲忓厓绱犲拰鐭跨墿瀵岄泦鐨勫悓娌夌Н鐏灞辩伆涓庢捣搴曞柗娴佸嶅悎鎴愬洜
鎽 瑕 鐓や腑甯搁噺銆佸井閲忓厓绱犲拰鐭跨墿鐨勫瘜闆嗗線寰鏄澶氱嶅湴璐ㄥ洜绱犲叡鍚屼綔鐢ㄧ殑缁撴灉銆傝繍鐢ㄤ綆娓╃伆鍖栥乆灏勭嚎琛嶅皠鍒嗘瀽銆佸甫鑳借氨浠鐨勬壂鎻忕數瀛愭樉寰闀溿侀愮骇鍖栧︽彁鍙栥佺數绂昏﹀悎绛夌诲瓙浣撹川璋辩瓑鏂规硶瀵逛簯鍗楃牃灞辨櫄浜屽彔涓栫叅鐨勭熆鐗╁﹀拰鍦扮悆鍖栧︾壒寰佽繘琛屼簡鐮旂┒锛屾彁鍑轰簡鐓や腑寰閲忓厓绱犲拰鐭跨墿瀵岄泦鐨勫悓娌夌Н鐏灞辩伆涓庢捣搴曞柗娴佸嶅悎妯″紡(鎴栨垚鍥犵被鍨)銆傜爺绌跺彂鐜帮紝鐮氬北鐭垮尯M9鐓ゅ眰纭鍒嗗惈閲忓緢楂(St锛宒=10.65%)锛屽睘浜庤秴楂樻湁鏈虹～鐓(So锛宒=9.51%)銆傜熆鐗╃粍鎴愪富瑕佹湁尾-鐭宠嫳鍓鍍忋侀忛暱鐭炽侀挔闀跨煶銆佺櫧浜戞瘝銆佷紛鍒╃煶銆侀粍閾佺熆浠ュ強灏戦噺鐨勯珮宀鐭炽佹枩闀跨煶銆侀挋闀侀粍闀跨煶銆侀噾绾㈢煶鍜岀墖閽犻摑鐭炽傜叅涓楂樺害瀵岄泦鐨勫井閲忓厓绱燜(841渭g/g)锛孷(567渭g/g)锛孋r(329渭g/g)锛孨i(74渭g/g)锛孧o(204渭g/g)鍜孶(153渭g/g)銆傝ョ叅涓鐨勭熆鐗╄川涓昏佹湁3涓鏉ユ簮:鈶犻珮娓╃煶鑻便侀忛暱鐭炽佺櫧浜戞瘝鍜屼紛鍒╃煶绛夋槸娉ョ偔鑱氱Н鏈熼棿閰告х伀灞辩伆闄嶈惤鍒版偿鐐娌兼辰鍚庣殑浜х墿;鈶￠挔闀跨煶鍜岀墖閽犻摑鐭充互鍙婁互涓婅秴甯稿瘜闆嗙殑寰閲忓厓绱犳槸鍦ㄦ偿鐐鑱氱Н鏈熼棿锛屽熀鎬-瓒呭熀鎬ф捣搴曞柗娴佷镜鍏ュ埌闂濉炵己姘х殑娉ョ偔娌兼辰涓鎵鑷;鈶㈢█鍦熷厓绱狅紝Nb锛孻锛孼r鍜孴iO2绛変翰鐭冲厓绱犳潵婧愪簬鐩嗗湴鍗楅儴鐨勮秺鍖楀彜闄嗐傞櫎浜嗙墿婧愪緵缁欎互澶栵紝鐮氬北鐭垮尯鐓ょ殑鐭跨墿瀛﹀拰鍦扮悆鍖栧﹀紓甯告槸鍚屾矇绉閰告х伀灞辩伆鍜屽熀鎬-瓒呭熀鎬ф捣搴曞柗娴佸叡鍚屼綔鐢ㄧ殑缁撴灉銆
浠诲痉璐荤叅宀╁﹀拰鐓ゅ湴鐞冨寲瀛﹁烘枃閫夎緫
鐓や腑甯搁噺鍜屽井閲忓厓绱犱互鍙婄熆鐗╂槸鐓ゅ舰鎴愬拰婕斿寲鍦拌川鍘嗗彶杩囩▼鐨勪骇鐗╋紝Ren绛変汉锛1锛鍜屼换寰疯椿绛変汉锛2锛鎬荤粨浜嗙叅涓寰閲忓厓绱犲瘜闆嗙殑鎴愬洜鏈虹悊锛屽苟鎻愬嚭浜5绉嶅瘜闆嗘ā寮忥紝鍗抽檰婧愬瘜闆嗗瀷銆佹矇绉鐨勭敓鐗╀綔鐢ㄥ瘜闆嗗瀷銆佸博娴嗙儹娑蹭綔鐢ㄥ瘜闆嗗瀷銆佹繁澶ф柇瑁-鐑娑蹭綔鐢ㄥ瘜闆嗗瀷鍜屽湴涓嬫按浣滅敤瀵岄泦鍨嬨傚惈鐓ゅ湴灞備腑鐨勭伀灞辩伆铓鍙橀粡鍦熷博澶圭煾(Tonstein)瀵圭爺绌跺尯鍩熷湴璐ㄥ巻鍙叉紨鍖栧拰鐓ゅ眰瀵规瘮绛夋柟闈㈠叿鏈夐噸瑕佷綔鐢锛3锛4锛銆傚逛腑鍥借タ鍗楀湴鍖烘櫄浜屽彔涓栫叅涓鍙戣偛鐨凾onstein鐨勭爺绌惰〃鏄锛4锝6锛锛屾櫄浜屽彔涓栨棭鏈熺殑鐏灞卞柗鍙戜互纰辨х伀灞辩伆涓轰富锛屾櫄浜屽彔涓栦腑鏅氭湡浠ラ吀鎬т负涓汇傜叅涓鐨凾onstein鍙鑳戒細瀵圭叅鐨勫湴鐞冨寲瀛︾壒寰佷骇鐢熼噸瑕佸奖鍝锛7锛銆傚奖鍝嶈タ鍗楀湴鍖烘櫄浜屽彔涓栫叅涓寰閲忛噾灞炲厓绱犲瘜闆嗙殑鍥犵礌寰堝氾紝浣嗕綆娓╃儹娑叉槸涓绘帶鍥犵礌锛8锛9锛銆傝祴瀛樺湪鐓や腑鐨勫悓娌夌Н鐏灞辩伆(鍒嗗竷鍦ㄧ叅涓鏈夋満璐ㄤ腑鐨勭伀灞辩伆锛屼笉鍖呮嫭Tonstein)鏈夎緝灏戞姤閬锛7锛锛岃屾捣搴曞柗娴佸圭叅涓鐭跨墿鍜屽厓绱犲瘜闆嗙殑褰卞搷灏氭湭瑙佽告姤閬撱傛湰鏂囧逛簯鍗楃牃灞卞眬闄愮⒊閰哥洂鍙板湴鍨嬬叅灞傜殑鐭跨墿瀛﹀拰鍦扮悆鍖栧﹁繘琛屼簡鐮旂┒锛屾彁鍑轰簡鐓や腑鐭跨墿鍜屽井閲忓厓绱犲瘜闆嗙殑鍚屾矇绉鐏灞辩伆涓庢捣搴曞柗娴佸嶅悎妯″紡銆傝ユ枃鎻愬嚭鐨勭叅涓寰閲忓厓绱犲拰鐭跨墿鐨勫瘜闆嗘ā寮忥紝鍙浠ヤ负鏂板瀷閲戝睘鐭垮簥鐨勫绘壘鎻愪緵鍊熼壌銆
涓銆佸湴璐ㄨ儗鏅
鐮氬北鐭垮尯浣嶄簬浜戝崡鐪佷笢鍗楅儴(鍥1)锛屽叾鍚鐓ゅ湴灞備负涓婁簩鍙犵粺鍚村跺潽缁(P2w)鍜岄暱鍏寸粍(P2ch)锛10锛锛岃ュ尯M9鐓ゅ眰鏄鍏稿瀷鐨勫眬闄愮⒊閰哥洂鍙板湴鍨嬬叅灞傘侻9鐓ゅ眰浣嶄簬涓婁簩鍙犵粺鍚村跺潽缁勭殑涓閮锛屽帤搴︿负1.91m锛屽叾椤舵澘涓哄瘜鍚鐢熺墿纰庡睉鐨勯殣鏅剁伆宀╋紝搴曟澘涓虹偔璐ㄦ偿宀╂垨鍚鐐娉ョ伆宀┿傚惈鐓ゆ矇绉鐨勪富瑕佺墿婧愭潵鑷鐩嗗湴鍗楅儴鐨勮秺鍖楀彜闄(鍥1)銆
鍥1 鐮氬北鐭垮尯浣嶇疆鍥惧拰鏅氫簩鍙犱笘鍙ゅ湴鐞嗗浘
浜屻佺爺绌舵柟娉
鍏遍噰闆嗙牃灞卞共娌矼9鐓ゅ眰鍏ㄥ眰鍒绘Ы鏍峰搧3涓锛岀紪鍙峰垎鍒涓篩S-1锛孻S-2鍜孻G銆傚悓鏃讹紝鑷涓婅屼笅鍏遍噰鍒嗗眰鍒绘Ы鏍峰搧3涓锛岀紪鍙峰垎鍒鏄痀-3-1锛孻-3-2鍜孻-3-3锛岃繖3涓鍒嗗眰鐨勫帤搴﹀垎鍒涓0.70锛0.67鍜0.54m銆
杩愮敤鍏夊︽樉寰闀溿佸甫鑳借氨浠鐨勬壂鎻忕數瀛愭樉寰闀溿佷綆娓╃伆鍖栧拰X灏勭嚎琛嶅皠浠瀵圭熆鐗╃殑绉嶇被銆佸瓨鍦ㄧ姸鎬佽繘琛屼簡鐮旂┒銆傚埄鐢ㄦ樉寰闀滃厜搴﹁″圭叅涓鏄惧井缁勫垎鐨勫舰鎬佸拰闀滆川缁勫弽灏勭巼杩涜屼簡娴嬪畾銆傝繍鐢╔灏勭嚎鑽у厜鍏夎氨浠瀵圭叅涓甯搁噺鍏冪礌鐨勫惈閲忚繘琛屼簡娴嬪畾锛孎鍜孒g鍒嗗埆杩愮敤绂诲瓙閫夋嫨鎬х數鏋佸拰鍐峰師瀛愬惛鏀跺厜璋辨硶杩涜屼簡娴嬪畾锛孋l閲囩敤鑹惧＋鍗℃贩鍚堝墏鐔旀牱-纭姘伴吀閽炬淮瀹氭硶娴嬪畾;B鍒╃敤鐢电昏﹀悎绛夌诲瓙浣撳師瀛愬彂灏勫厜璋辨祴瀹;鍏朵粬寰閲忓厓绱犻噰鐢ㄧ數绂昏﹀悎绛夌诲瓙浣撹川璋辫繘琛屼簡娴嬪畾銆
涓夈佺粨鏋滀笌璁ㄨ
1.鐓ゅ寲瀛︾壒寰
浜戝崡鐮氬北鏅氫簩鍙犱笘M9鐓ゅ睘浜庝腑鐏(27.51%)銆侀珮纭(10.65%)鐨勯珮鐓ゅ寲绋嬪害鐨勭儫鐓(璐鐓)銆傜敱浜嶮9鐓ゅ眰涓鏈夋満纭鍚閲忛珮杈9.51%锛屽張绉颁箣涓鸿秴楂樻湁鏈虹～鐓(琛1)銆傝繖绉嶈秴楂樻湁鏈虹～鐓ゅ湪鑷鐒剁晫涓闈炲父缃曡併傚湪涓鍥斤紝姝ょ被鍨嬬叅浠呭湪璐靛窞璐靛畾(So锛宒=8.57%)鍜屽箍瑗垮悎灞(So锛宒=3.42%锝6.46%)鏈夋姤閬锛11锛12锛銆
琛1 浜戝崡鐮氬北鏅氫簩鍙犱笘M9鐓ょ殑宸ヤ笟鍒嗘瀽銆佸叏纭鍜屽舰鎬佺～娴嬭瘯缁撴灉 鍗曚綅:%
娉:6涓鏍峰搧鍧囧.M鈥旀按鍒;A鈥旂伆鍒;V鈥旀尌鍙戝垎;St鈥斿叏纭;Ss鈥旂～閰哥洂纭;Sp鈥旂～鍖栫墿纭;So鈥旀湁鏈虹～;ad鈥斿垎鏋愬熀;d鈥斿共鐕ュ熀;daf鈥斿共鐕ユ棤鐏板熀銆
2.鐓や腑鐭跨墿鐨勭嶇被銆佽祴瀛樼壒寰佸拰鎴愬洜
鐓や腑甯歌佺殑鐭跨墿涓鑸鏈夐粡鍦熺熆鐗┿佺～鍖栫墿鐭跨墿銆佺煶鑻卞拰鏂硅В鐭锛13锛銆傚埄鐢ㄤ綆娓╃伆鍖+X灏勭嚎琛嶅皠鍒嗘瀽銆佸厜瀛︽樉寰闀滃拰甯﹁兘璋变华鐨勬壂鎻忕數瀛愭樉寰闀滆傚療鍚庡彂鐜帮紝鐮氬北M9鐓ゅ眰涓鐨勭熆鐗╃粍鍚堣緝涓哄紓甯革紝涓昏佺熆鐗╂湁閫忛暱鐭炽佄-鐭宠嫳鍓鍍忋佺櫧浜戞瘝銆佷紛鍒╃煶銆侀挔闀跨煶銆侀粍閾佺熆锛岃繕鏈夊皯閲忕殑鐗囬挔閾濈煶銆佹枩闀跨煶銆侀挋闀侀粍闀跨煶銆侀攼閽涚熆鍜岄噾绾㈢煶銆
榛勯搧鐭:涓昏佸憟娴告煋鐘舵垨鑾撶悆鐘跺垎甯冨湪鍩鸿川闀滆川浣撲腑锛屽叾绮掑緞杈冨皬锛屽ぇ閮ㄥ垎灏忎簬20渭m銆傜叅涓榛勯搧鐭跨殑璧嬪瓨褰㈡佽〃鏄庯紝瀹冨睘浜庢捣姘村奖鍝嶄笅鐨勪骇鐗┿傛偿鐐鑱氱Н鏈熼棿锛屾捣姘翠腑鐨勭～閰告牴绂诲瓙琚纭閰哥洂杩樺師鑿岃繕鍘熸垚纭鍖栨阿鍚庝笌娌兼辰涓鐨凢e绂诲瓙鍙嶅簲鑰屽舰鎴锛14锛銆
尾-鐭宠嫳鍓鍍:涓昏佸憟缁嗗皬鐨勩佹櫠鍨嬭緝濂界殑棰楃矑鍒嗗竷鍦ㄥ熀璐ㄩ暅璐ㄤ綋涓锛屽叾缁濆ぇ閮ㄥ垎棰楃矑灏忎簬10渭m锛屾í鍒囬潰杩戝叚杈瑰舰(鍥2(a))锛屾湁鐨勬湁鐔旇殌鐜拌薄銆佹煴闈涓嶅彂鑲层備粠鍏跺舰鎬佺壒寰佸彲浠ユ帹鏂灞炰簬楂樻俯鎴愬洜銆
閫忛暱鐭:绮掑緞杈冨皬锛岀粷澶ч儴鍒嗗皬浜10渭m锛屾湁鐨勬櫠褰淇濆瓨杈冨ソ(鍥2(b)锛(c))锛屾湁鐨勫彂鐢熶簡鐔旇殌锛岃鐔旇殌鐨勯忛暱鐭虫湁鏃朵粎淇濈暀妯＄硦鐨勫栧舰锛屾湁鐨勯忛暱鐭崇啍铓鐜拌薄杈冧负涓ラ噸锛屼粎鐣欐湁娈嬬己涓嶅叏鐨勮竟缂橈紝鍐呴儴琚閽犻暱鐭虫墍鏇夸唬鎴栫墖閽犻摑鐭(NaAl(OH)2CO3)鎵鍏呭～(鍥2(c))銆
鐧戒簯姣:鍛堥暱鏉＄姸鍒嗗竷鍦ㄥ熀璐ㄩ暅璐ㄤ綋涓銆
閽犻暱鐭:鏅跺舰杈冮忛暱鐭冲畬鏁(鍥2(d))锛岀畝鍗曞弻鏅跺彂鑲诧紝閮ㄥ垎閽犻暱鐭冲彂鐢熶簡鐔旇殌鐜拌薄(鍥2(c))锛屾湁鐨勯挔闀跨煶鍏呭～鍦ㄨ鐔旇殌浜嗙殑閫忛暱鐭冲唴閮ㄣ
浼婂埄鐭:鍛堜笉瑙勫垯鍥㈠潡鐘躲侀暱鏉＄姸銆佺诞鍑濈姸(鍥2(e))鎴栨蹈鏌撶姸鍒嗗竷鍦ㄧ叅鐨勫熀璐ㄩ暅璐ㄤ綋涓銆
姝ゅ栵紝M9鐓ゅ眰涓杩樻湁灏戦噺鐨勬枩闀跨煶銆侀噾绾㈢煶銆侀挋闀侀粍闀跨煶鍜岄珮宀鐭崇瓑鐭跨墿鍒嗗竷鍦ㄥ熀璐ㄩ暅璐ㄤ綋涓銆
铏界劧鐓ょ郴鍦板眰涓閰告х伀灞辩伆铓鍙橀粡鍦熷博澶圭煾涓鐨勯珮娓╃煶鑻遍潪甯告櫘閬锛3锛15锛锛屼絾鍦ㄧ叅涓鍜屾湁鏈鸿川绱у瘑鑱旂郴鐨勯珮娓╂垚鍥犵殑鐭宠嫳鍗撮矞鏈夋姤閬撱傜牃灞盡9鐓ゅ眰涓楂樻俯鎴愬洜鐨勭煶鑻卞叾澶栧舰浠嶇劧渚澪茬煶鑻辨垚鍓鍍(鍥2(a))銆偽茬煶鑻卞拰閫忛暱鐭虫槸楂樻俯鐩哥殑浜х墿銆傝ョ叅涓楂樻俯鐭宠嫳-閫忛暱鐭-鐧戒簯姣嶇熆鐗╃粍鍚堟槸娉ョ偔鑱氱Н鏈熼棿閰告х伀灞辩伆闄嶈惤鍒版布娉戒腑鐨勪骇鐗┿傜敱浜庤繖浜涚熆鐗╃殑绮掑緞寰堝皬锛屽苟涓斿潎鍖鍦板垎甯冨湪鐓ょ殑鏈夋満璐ㄤ腑锛屾帹娴嬪綋鏃剁殑鐏灞卞彛璺濇布娉借緝杩滐紝骞朵笖闄嶈惤鍒版布娉戒腑鐨勭伀灞辩伆鐨勬暟閲忚緝灏戯紝灏氫笉瓒充互褰㈡垚鎵璋撶殑鐏灞辩伆铓鍙橀粡鍦熷博澶圭煾(Tonstein)銆傚湪M9鐓ゅ眰涓灏氭湭鍙戠幇Tonstein灞傦紝鐮氬北鐭垮尯浣嶄簬涓嶼hou绛変汉锛4锛鎵鍦堝畾鐨勮タ鍗楀湴鍖篢onstein鐨勫垎甯冭寖鍥翠箣澶栵紝鑰屽湪姝よ寖鍥村唴锛屾櫄浜屽彔涓栫伀灞辨椿鍔ㄨ緝涓哄己鐑堬紝鍦ㄧ叅灞備腑褰㈡垚澶氬眰鐨凾onstein銆
鍥2 M9鐓や腑鐨勭熆鐗╄祴瀛樼壒寰
闄嗘簮纰庡睉渚涚粰鍜屽悗鐢熶綔鐢ㄧ瓑鍧囧彲鍦ㄧ叅涓褰㈡垚浼婂埄鐭锛13锛銆備絾M9鐓ゅ眰涓鐨勪紛鍒╃煶骞堕潪闄嗘簮纰庡睉鎴愬洜锛屼篃涓嶆槸鍚庢湡鐑娑蹭綔鐢ㄧ殑浜х墿銆傞檷钀藉埌M9鐓ゅ眰鐨勬布娉戒腑鐨勯吀鎬х伀灞辩伆鐜荤拑璐ㄥ湪娉ョ偔鑱氱Н鏈熼棿鍜屾垚宀╀綔鐢ㄦ棭鏈熻殌鍙樺舰鎴愰珮宀鐭筹紝闅忕潃鎴愬博浣滅敤鐨勫炲己鍜屽湪鍋忕⒈鎬х殑浠嬭川鐜澧冩潯浠朵笅锛屽ぇ閮ㄥ垎楂樺箔鐭宠浆鍙樹负浼婂埄鐭筹紝鏈変簺浼婂埄鐭宠繕淇濈暀鐫鐏灞辩伆绲鍑濈姸鐨勭粨鏋勭壒寰(鍥2(e))銆侭urger绛変汉锛5锛銆佸懆涔夊钩鍜屼换鍙嬭皡锛6锛鐨勭爺绌惰〃鏄庯紝鍦ㄤ簯鍗椾笢閮ㄥ拰璐靛窞瑗块儴涓婁簩鍙犵粺鐓ょ郴鍦板眰鐨凾onstein涓榛忓湡鐭跨墿(楂樺箔鐭-浼婂埄鐭)鐨勭粍鎴愭瘮渚嬩笌鐓ょ殑鍙樿川绋嬪害瀵嗗垏鐩稿叧锛屽湪鐑熺叅闃舵碉紝楂樺箔鐭冲崰浼樺娍锛屽埌鏃犵儫鐓ら樁娈碉紝缁濆ぇ閮ㄥ垎楂樺箔鐭宠殌鍙樹负浼婂埄鐭炽傜牃灞盡9鐓や腑鐏灞辩伆鎬ц川鍜岃タ鍗楀湴鍖虹殑鐏灞卞柗鍙戠墿鐨勭壒寰佺浉鍚诲悎锛屽嵆鍦ㄦ櫄浜屽彔涓栦腑鏅氭湡浠ラ吀鎬т负涓汇
鐓や腑鐨勯暱鐭冲拰鐧戒簯姣嶄竴鑸琚璁や负鏄闄嗘簮纰庡睉鎴愬洜鐨勭熆鐗锛13锛16锛銆備絾鐮氬北M9鐓ゅ眰涓鐨勯暱鐭冲苟闈為檰婧愮庡睉鎴愬洜銆侻9鐓や腑鐨勯挔闀跨煶涓庣伀灞辨垚鍥犵殑閫忛暱鐭炽侀珮娓╃煶鑻变害涓嶆槸鍚屾湡鎴愬洜鐨勪骇鐗┿傞挔闀跨煶鏈夋椂鍏呭～鍦ㄨ鐔旇殌鐨勯忛暱鐭冲唴閮锛屾槸鍦ㄩ忛暱鐭冲彂鐢熸憾铓鍚庡舰鎴愮殑锛屽叾褰㈡垚鏃堕棿鏅氫簬閫忛暱鐭筹紝琛ㄦ槑閽犻暱鐭虫槸浠庣儹娑蹭腑鑷鐢熺殑銆傚洜姝わ紝鍙浠ユ帹鏂鍦ㄦ偿鐐鑱氱Н鏈熼棿锛岀伀灞辩伆闄嶈惤鍒版偿鐐娌兼辰骞朵笖缁忚繃浜嗕竴瀹氱殑铓鍙樹綔鐢ㄥ悗锛屽張鏈夊熀鎬-瓒呭熀鎬х殑娴峰簳鍠锋祦褰㈡垚鐨勭儹娑茶繘鍏ュ埌娉ョ偔娌兼辰涓锛屽舰鎴愪簡閽犻暱鐭冲拰灏戦噺鐨勭墖閽犻摑鐭冲拰鏂滈暱鐭崇瓑鐭跨墿銆傜墖閽犻摑鐭冲湪鐓や腑灏氭湭瑙佽告姤閬锛13锛17锛18锛锛屾槸涓绉嶆按鐑鎴愬洜鐨勭熆鐗锛19锝21锛銆傜墖閽犻摑鐭宠板綍浜嗘繁閮ㄥ箶婧-娴呴儴澹虫簮涔嬮棿鐨勭墿璐ㄨ浆绉伙紝鏄娴佷綋杩愮Щ鍚庣暀涓嬬殑浜х墿锛屽苟涓斿舰鎴愪簬瀵岄挔绂诲瓙鐨勭⒈鎬ф祦浣撲粙璐ㄦ潯浠锛21锛22锛锛岃ョ熆鐗╃殑瀛樺湪杩涗竴姝ヨ瘉鏄庝簡娴峰簳鍠锋祦渚靛叆鍒颁簡娉ョ偔娌兼辰銆
鐗囬挔閾濈煶鍜岄挔闀跨煶鐨勮祴瀛樼姸鎬佹帓闄や簡杩欎袱绉嶇熆鐗╁睘浜庡悗鐢熺儹娑茬殑鍙鑳芥:鈶燤9鐓や腑鐨勫悗鐢熻傞殭鏋佷笉鍙戣偛锛屽皻鏈鍙戠幇鍏呭～浜庡悗鐢熻傞殭鐨勯暱鐭冲拰鐗囬挔閾濈煶;鈶￠挔闀跨煶鍦ㄧ叅灞備腑椤哄眰鐞嗗垎甯(鍥2(f))锛屾樉绀哄嚭鍚屾矇绉鐨勭壒寰侊紝鑰岄潪鍚庣敓鐑娑叉垚鍥;鈶㈣ョ叅涓鐨勭熆鐗╃粍鎴愮殑骞抽潰鍒嗗竷鐨勫樊寮傛ф瀬涓嶆槑鏄撅紝閽犻暱鐭冲湪璇ョ叅灞備腑鏅閬嶅瓨鍦锛屽湪鐮旂┒鑰1988骞撮噰闆嗙殑鏍峰搧鍜2006骞撮噰闆嗙殑鏍峰搧涓鍧囧瘜闆嗛挔闀跨煶绛夌熆鐗(鏍峰搧閲囬泦闂撮殧18a);鑰屽悗鐢熺儹娑叉垚鍥犵殑鐭跨墿寰寰鍦ㄧ叅灞備腑鍏锋湁灞閮ㄥ瘜闆嗙殑鐗瑰緛锛屽惈閲忓垎寮傛槑鏄俱
3.鐓や腑甯搁噺鍜屽井閲忓厓绱犵殑涓板害銆佽祴瀛樼姸鎬佸拰鎴愬洜
琛2鍒楀嚭浜嗙牃灞盡9鐓や腑甯搁噺鍏冪礌鍜屽井閲忓厓绱犵殑鍚閲忓強鍏朵笌涓鍥藉ぇ閮ㄥ垎鐓ゃ佷笘鐣屽ぇ閮ㄥ垎鐓ょ殑瀵规瘮銆備粠涓鍙浠ョ湅鍑猴紝鐮氬北骞叉渤M9鐓や腑鐨勫厓绱犳湁濡備笅鐗瑰緛:涓庝腑鍥藉ぇ閮ㄥ垎鐓ゅ拰涓栫晫澶ч儴鍒嗙叅涓寰閲忓厓绱犵殑鍧囧肩浉姣旓紝鐮氬北鐓や腑F(841渭g/g)锛孷(567渭g/g)锛孋r(329渭g/g)锛孨i(74渭g/g)锛孧o(204渭g/g)鍜孶(153渭g/g)绛夊井閲忓厓绱犵殑鍚閲忚秴甯稿瘜闆(琛2)銆傝ョ叅涓璙锛孋r锛孧o鍜孶鐨勫潎鍊煎垎鍒鏄涓鍥藉父瑙佺叅鐨16.2鍊嶃21.4鍊嶃63.9鍊嶅拰63.5鍊嶃
铏界劧闄嗘簮纰庡睉渚涚粰閫氬父鏄鐓や腑寰閲忓厓绱犵殑涓涓閲嶈佹潵婧愶紝鐮氬北M9鐓や腑鐨勭█鍦熷厓绱狅紝Nb锛孻锛孼r鍜孴iO2绛変翰鐭冲厓绱犲弽鏄犱簡瓒婂寳鍙ら檰鐗╂簮鐗╄川缁勬垚鐗瑰緛銆傝秺鍖楀彜闄嗘槸鍔犻噷涓滆ざ鐨卞甫娉告睙甯︼紝浠ラ吀鎬у博浣撲负涓锛25锛26锛銆備絾鐮氬北鐓や腑楂樺惈閲忕殑V锛孨i锛孋r锛孧o鍜孶鏄涓嶈兘鐢ㄩ檰婧愪緵缁欐墍鑳借В閲婄殑銆備笌瓒呭熀鎬у拰鍩烘у博鐩告瘮锛岄吀鎬у博涓鐨刅锛孨i锛孧o锛孋r绛夊厓绱犲潎杈冧綆锛孶鐨勫惈閲忚櫧鐒惰緝楂橈紝浣嗗叾鍚閲忎篃浠呬负3.5渭g/g锛27锛锛屼笉瓒充互鎻愪緵鐓や腑濡傛ら珮鍚閲忕殑U銆
杩欎簺楂樺惈閲忕殑鍏冪礌涔熶笉鏄涓婇潰鎵鍙欒堪鐨勯吀鎬х伀灞辩伆闄嶈惤鍒版偿鐐娌兼辰褰㈡垚鐨勶紝閰告х伀灞辩伆骞朵笉瀵岄泦杩欎簺鍏冪礌锛屼綍鍐甸檷钀藉埌娉ョ偔娌兼辰涓鐨勯吀鎬х伀灞辩伆鐨勯噺姣旇緝灏戙
灏氭棤璇佹嵁琛ㄦ槑杩欎簺鍏冪礌鏄鍦板栨潵婧愩傝繖浜涘厓绱(鍖呮嫭S鍦ㄥ唴)涔熶笉鏄姝ｅ父娴锋按鑳藉熸彁渚涚殑锛屾捣姘翠腑鐨勭～閰哥洂娴撳害鏄涓瀹氱殑锛屽苟涓旀偿鐐鑱氱Н鏄鍦ㄤ竴绉嶆粸鐣欑殑銆佸彈闄愮殑灞闄愮⒊閰哥洂鍙板湴锛屽奖鍝嶆偿鐐娌兼辰鐨勬柊椴滄捣姘村苟涓嶈兘寰楀埌鍙婃椂鐨勮ˉ鍏呫
琛2 鐮氬北M9鐓ゅ眰鍏冪礌鐨勫惈閲忓強鍏朵笌涓鍥藉ぇ閮ㄥ垎鐓ゃ佷笘鐣屽ぇ閮ㄥ垎鐓ょ殑瀵规瘮
鐮氬北M9鐓ゅ眰涓瀵岄泦鐨勫厓绱犲強鍏跺厓绱犵殑缁勫悎鐗瑰緛绫讳技浜庝腑鍥藉崡鏂规棭瀵掓︾邯鐨勯粦鑹查〉宀(鍖呮嫭鐭崇叅)锛岀劧鑰岀牃灞辩叅涓鍏冪礌姣旈粦鑹查〉宀╀腑鐨勮祴瀛樺舰寮忓拰鏉ユ簮澶嶆潅寰楀氾紝鏃㈡湁鐏灞辩殑銆侀檰婧愮庡睉鐨勩佺敓鐗╃殑銆佹捣姘寸殑锛岃繕鏈夋捣搴曞柗娴佺殑銆傜牃灞辩叅鐨勫湴鐞冨寲瀛﹀紓甯稿彲鑳芥槸鍦ㄦ偿鐐鑱氱Н鏈熼棿锛屾捣搴曞柗娴佹惡甯︾殑閲戝睘鍏冪礌V锛孨i锛孧o锛孶锛孋r浠ュ強S鍜孎绛夋部娣卞ぇ鏂瑁傛惉杩愭矇绉鑷虫偿鐐娌兼辰鐨勭粨鏋溿傛捣搴曞柗娴佷粠闀侀搧璐-瓒呴晛閾佽川宀╀腑娣鍙栦簡V锛孨i锛孋u鍜孧o锛屽苟鍙鑳戒笌涓嬩紡鐨勫瘜U鐨勫博娴嗗眰鎻愪緵鐨勭墿璐ㄦ贩鍚堝湪涓璧凤紝鎼杩愭矇绉鍒板眬闄愮⒊閰哥洂鍙板湴鐨勬偿鐐娌兼辰涓锛岀己姘х殑鐜澧冨拰娌兼辰涓涓板瘜鐨勬湁鏈鸿川(楂樼瓑妞嶇墿鍜屼綆绛夌敓鐗╄弻钘荤被)涓哄厓绱犵殑闀挎椂闂存椿鍖栧拰瀵岄泦鎻愪緵浜嗘潯浠躲傞矋瀛︽槶绛変汉锛28锛鐮旂┒琛ㄦ槑锛屾捣搴曞柗娴佷綔鐢ㄥ彲甯︽潵澶ч噺鐨刄鍏冪礌銆
铏界劧浣庣瓑鐢熺墿瀵规湁鏈虹～鍜屼竴浜涢噾灞炲厓绱犲瘜闆嗘湁璐＄尞锛屼絾M9鐓や腑濡傛ら珮鍚閲忕殑纭鍜岄噾灞炲厓绱犱篃涓嶆槸纭缁嗚弻鎵鑳藉熸彁渚涚殑銆傝ョ叅灞傜殑骞查叒鏍刮13C鈥(PDB)鍊间负锛22.8鈥帮綖锛23.7鈥帮紝N鐨勫惈閲忓苟涓嶉珮(0.67%锝0.69%)锛屽叿鏈夎厫娈栫叅鐨勭壒寰侊紝鍥犳ゆ垚鐓ゆ嶇墿鐨勪富浣撹繕鏄楂樼瓑妞嶇墿銆備絾鏄锛岃弻钘荤被鍦ㄥ叾鐢熼暱鍜屾讳骸鍚庨檷瑙ｈ繃绋嬩腑锛屽彲鍦ㄥ厓绱犲瘜闆嗐佹敼鍙樼幆澧僷H鍜孍h鍊笺佹敼鍙樻按浣撲腑鍏冪礌骞宠绯荤粺鍜屽厓绱犳矇娣绛夋柟闈㈠圭叅涓鏈夋満纭鍜岄噾灞炲厓绱犵殑瀵岄泦鍙戞尌閲嶈佷綔鐢ㄣ
鍦ㄥ井閲忓厓绱犵殑缁勫悎鏂归潰锛屼互鏈夋満鎬佺粨鍚堢殑V/(V+Ni)=0.88锛岀己姘х幆澧冧腑鏈夋満璐ㄧ殑V/(V+Ni)>0.5锛岃屾哀鍖栨潯浠朵笅<0.4锛29锛銆備粠鐮氬北M9鐓ょ殑U/Th鍏崇郴(鍥3)涓鍙浠ョ湅鍑猴紝鎶曠偣鍧囪惤鍏U/Th=1锝100鍖哄煙锛屽彟澶栵紝U/Th姣斿煎緢楂(8.9锝35.2)锛岃存槑娉ョ偔鑱氱Н鏃跺彈鍒扮儹娑插奖鍝嶈緝涓哄己鐑锛30锛31锛銆傜敤Th-U鐨勫叧绯诲紡Ua=UTotal鈥揟h/3(鍏朵腑Ua涓鸿嚜鐢烾)鍙浠ヨ存槑缂烘哀鏉′欢锛32锛锛孧9鐓ょ殑Ua涓107锝176渭g/g锛岃孧7鐓ょ殑Ua浠呬负17渭g/g锛岃〃鏄嶮9鐓ょ殑娉ョ偔鑱氱Н鏃舵樉钁楃己姘с
灏嗙牃灞盡9鐓ゅ眰涓鐨刏n锛孨i鍜孋o鍏冪礌鍚閲忔姇鍏Cronan鐨刏n-Ni-Co涓夊厓鍥句腑(鍥4)锛岃繖浜涚偣鍧囪惤鍏ョ儹姘存矇绉鍖猴紝鏄剧ず浜嗙儹姘存矇绉鐨勭壒寰锛33锛銆
鍥3 鐮氬北M9鐓ゅ眰鐨刄/Th鍏崇郴鍥
鍥4 鐮氬北M9鐓ゅ眰鐨刏n-Ni-Co鍥捐В
鍏充簬纭鐨勬潵婧愬拰璧嬪瓨鐘舵侊紝鐢变簬鐜拌岀殑鏈夋満纭鍚閲忕殑纭瀹氭柟娉(GB/T214锛1996锛孏B/T215锛2003鍜孉STMD3177/4239鍜孌2492锛2)鏄鐢ㄥ叏纭鍑忕～鍖栫墿纭鍜岀～閰哥洂纭鎵鑾峰緱鐨勶紝杩欎簺鏂规硶灏氫笉鑳借瘉鏄庤繖浜涚～灏辨槸鏈夋満鐨勩傜牃灞盡9鐓や腑鐨勮祴瀛樼姸鎬佸煎緱娣卞叆鐮旂┒銆傝繖浜涢珮鍚閲忕殑纭鍙鑳芥槸娴峰簳鐑娉夊甫鍏ュ埌灏侀棴鐨勬布娉戒腑锛屽苟涓斿潎鍖鍦板垎甯冨湪鐓ょ殑鏈夋満璐ㄤ腑锛岃岃璁や负鏄鎵璋撶殑鈥滄湁鏈虹～鈥濄
缁间笂鎵杩帮紝浜戝崡鐮氬北M9鐓ゅ眰鐨勭熆鐗╃粍鎴愬拰涓浜涘厓绱犵殑瓒呭父瀵岄泦鏄鍚屾矇绉鐏灞辩伆涓庢捣搴曞柗娴佸叡鍚屼綔鐢ㄧ殑缁撴灉锛岃ョ叅灞傜熆鐗╄川鐨勫瘜闆嗘垚鍥犳槸涓绉嶆柊鐨勫嶅悎瀵岄泦妯″紡銆傝嚦浜庤吹宸炶吹瀹氬拰骞胯タ鍚堝北鏅氫簩鍙犱笘鐓ゆ槸鍚﹀彈鍒板悓娌夌Н閰告х伀灞辩伆鐨勫奖鍝嶈繕闇杩涗竴姝ョ爺绌躲
鍦ㄧ叅涓寰閲忓厓绱犵殑鍒╃敤鏂归潰锛岀敱浜庤ョ叅涓鐨刅锛孋r鍜孶鍚閲忓緢楂橈紝瀹冧滑鍦ㄧ叅鐨勭噧鐑т骇鐗(濡傞炵伆)涓鍙鑳借繘涓姝ュ瘜闆嗭紝濡傛灉鑳藉硅繖浜涘厓绱犺繘琛屾彁鍙栵紝鍙浠ュ疄鐜扮叅鐐缁忔祹鐨勮壇鎬у惊鐜鍙戝睍锛屼篃涓烘柊绫诲瀷鐨勯噾灞炵熆搴婄爺鍙戞彁渚涘熼壌銆
鍥涖佺粨璁
浜戝崡鐮氬北M9鐓ゆ槸灞闄愮⒊閰哥洂鍙板湴鍩虹涓婂舰鎴愮殑鐓ゅ眰锛屽睘浜庤秴楂樷滄湁鏈虹～鈥濈叅銆傝ョ叅涓鐭跨墿鐨勭嶇被鍜岀粍鍚堢壒寰(尾-鐭宠嫳鍓鍍忋侀忛暱鐭炽侀挔闀跨煶銆佺櫧浜戞瘝銆佷紛鍒╃煶銆佹枩闀跨煶銆侀挋闀侀粍闀跨煶銆佺墖閽犻摑鐭)鍜岃秴甯稿瘜闆嗗井閲忓厓绱(F锛孷锛孋r锛孨i锛孧o鍜孶)鏄鍚屾矇绉閰告х伀灞辩伆鍜屾捣搴曞柗娴佸叡鍚屼綔鐢ㄧ殑缁撴灉銆傝ョ叅灞備腑鐨勫井閲忓厓绱犲拰鐭跨墿鐨勫瘜闆嗘垚鍥犳満鍒舵槸涓绉嶆柊鐨勫瘜闆嗘ā寮(鎴栨垚鍥犵被鍨)銆
鍙 鑰 鏂 鐚
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( 鏈鏂囩敱浠ｄ笘宄般佷换寰疯椿銆佸懆涔夊钩銆丆hen-Lin Chou銆佺帇瑗垮媰銆佽档钑俱佹湵鍏翠紵鍚堣憲锛屽師杞姐婄戝﹂氭姤銆嬶紝2008 骞寸 53 鍗风 24 鏈)